A redox-switchable [2]rotaxane in a liquid-crystalline state.

نویسندگان

  • Takuma Yasuda
  • Kana Tanabe
  • Toru Tsuji
  • Karla K Coti
  • Ivan Aprahamian
  • J Fraser Stoddart
  • Takashi Kato
چکیده

Redox-driven mechanical movement, which has been achieved for a liquid-crystalline (LC) bistable [2]rotaxane in the LC phase, is accompanied by obvious electrochromism (electrochemically induced changes in color) of the material. The dumbbell-shaped LC [2]rotaxane with redox-active moieties, which interlocks with an ionic macrocycle, forms ordered redox-active condensed states.

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عنوان ژورنال:
  • Chemical communications

دوره 46 8  شماره 

صفحات  -

تاریخ انتشار 2010